Surface Preparation Prior to Plasma Vapor Deposition, Thermal Spray, and Related Engineered Coatings
• customize, select vacuum solvent system
• critical cleaning of bearings, biomedical devices, aircraft engines
Plasma Technology Incorporated, headquartered in Torrance, CA, specializes in plasma vapor deposition, physical vapor deposition, and ion vapor deposition. Applications include bearings, biomedical devices, aircraft engines, as well as an array of aircraft and consumer products. Substrates include stainless steel, aluminum, magnesium, and a number of alloys. Product configuration ranges from miniature bearings and small complex, biomedical-related components to aircraft engines, canning chucks, and five-foot long shafts. Soils include an assortment of organic oils, water-soluble oils, and fingerprints. Levels and mixtures of soils are variable. As such, the facility is best characterized as a very specialized job shop with critical requirements for precision cleaning, surface preparation, and product performance. The company had been using vapor phase cleaning in a chlorinated solvent. While the system provided good solvent containment, stringent local environmental constraints precluded use of common chlorinated solvents or of VOC’s (volatile organic compounds) in their open-top system. Some components are appropriate for aqueous cleaning; others require solvent cleaning.
The company considered several airless vacuum systems as well as a flammable
(low flashpoint) solvent system using acetone. Acetone could have been
an economical, VOC-exempt option. However, substrate compatibility
issues preclude the use
of heated acetone for this particular application. Four airless solvent
systems were evaluated in terms of performance, flexibility to meet
the diverse product
line, reliability, and cost.
A custom system including vapor phase, spray, and immersion cleaning
with ultrasonics was selected. During initial installation and process
optimization, BFK Solutions
assisted in troubleshooting filtration issues and in working with the
equipment vendor to make appropriate equipment modifications.
The system is now in routine use. There has been good employee acceptance, the process runs smoothly with miniscule release of solvent to the air.
References:
“Compliance and Performance: Selecting and Optimizing a Contained Cleaning System,” with B. Dowell, S. Norris, and J. Unmack,” invited presentation, International Thermal Spray Association, Las Vegas, NV, October 31, 2003 [link to presentation]
“Case Study: Cleaning Process Prior to PVD of Critical Metal Substrates,” Bob Dowell, Plasma Technology; Steve Norris, Plasma Technology; Jim Unmack, Unmack Corporation; and Barbara Kanegsberg, BFK Solutions, Presentation and Proceedings, CleanTech03, Chicago, Il, March, 2003.
“Choosing a Reliable, Environmentally-Preferred Process for Cleaning Prior to PVD,” Bob Dowell, Plasma Technology; Steve Norris, Plasma Technology; Jim Unmack, Unmack Corporation; and Barbara Kanegsberg, BFK Solutions, presentation, Thirteenth Annual International Workshop on Solvent Substitution and The Elimination of Toxic Substances and Emissions, Scottsdale, AZ, December, 2002.
Bearing Manufacture
• Evaluate, improve process flow
• Resolve inefficiencies due to conflicting soils, solvents
• Locate and resolve critical contamination sources
• Results:
improved contamination control
simpler cleaning process
A leading manufacturer of precision bearings for military
and NASA applications had an unacceptable failure rate of parts due to
contamination of process
baths, fixturing, and equipment. BFK Solutions evaluated the total
process flow and determined that much of the contamination was due
to having both
oil-based and water-based lubricants at various stages of manufacture.
The combination of lubricants and other contaminants formed a complex,
adherent
mixture which was difficult to remove. Suggested modifications included
changing process fluids and process flow. The modifications also
greatly extend the
lifetime of the cleaning solutions.
One problem was that the selected lubricant had changed, but the associated cleaning steps remained the same. Notably, the major, automated cleaning system contained a solvent step followed by several aqueous steps. The solvent had been added for historical reasons, to remove a metal working fluid which was no longer used. Continued use of solvent resulted in undesirable emulsions and precipitate. This resulted in inefficient cleaning and shortened bath life. The solvent cleaning step was eliminated. In addition, recontamination of parts at a critical point in the process was corrected by preventive maintenance and a slight variation in process flow.
Repair, Refurbishing, Precision Pumps; Conversion from Solvent to Aqueous
Processes
• Replace restricted solvents
• Implement steel shot, aqueous, and steam cleaning
• Improve depainting process
• Remove oils, heavy lapping compounds
Western Hydrostatics, Riverside, CA, is a growing company that rebuilds pumps for high-end, engineering applications. Because the company is in Southern California, project goals included elimination of cleaning with mineral spirits or any other solvent which is considered a VOC (volatile organic compound). In addition, management wanted to optimize the de-painting and rust removal process, and find efficient, cost effective methods to remove heavy machining oils, assorted dirt, and heavy lapping compound.
Depainting, general cleaning, and precision cleaning of a variety of
metal parts were evaluated. This project involved site visits
to similar applications
to compare equipment performance as well as in-house evaluation.
In addition, the heavy lapping compound was successfully replaced
with one that could
readily be removed with water-based cleaning agents. While
there was initial concern on the part of employees about process
changes, choosing
effective
products and involving the employees resulted in eventual
enthusiastic acceptance.
Consulting for this ambitious, extensive solvent substitution
project, particularly with a relatively small company,
required coordination
with upper management,
supervisors, and assemblers. A combination of non-solvent
and aqueous cleaning processes have been successfully adopted
at
Western Hydrostatics.
These include
steel-shot impingement, aqueous cleaning, and steam cleaning.
Reference:
“Hydrostatic Pump Rebuild: Implementing Aqueous, Steam, and Solvent Free Processes,” Barbara Kanegsberg and Pat Maluso, Western Hydrostatics, presentation, Tenth Annual International Workshop on Solvent Substitution and the Elimination of Toxic Substances and Emissions, Scottsdale, AZ, September 13 - 16, 1999.
Assembly and Repair: Refrigeration Equipment
• replace solvents having regulatory constraints
• implement aqueous cleaning with steam cleaning
• implement solvent cleaning
The company produces some 90% of the airline galley refrigeration equipment in use world-wide; and they set processes for field repair by airline technicians world-wide. The goals of the project included implementing reliable, cost-effective cleaning processes, replacing chemicals which with cumbersome regulatory restrictions, expanding aqueous and non-solvent cleaning wherever feasible, and standardizing processes for in-house cleaning and field repair.
Process replacement involved a combination of cleaning tools. After
in-house evaluations of a number of products,
aqueous cleaning was standardized and
expanded. Steam cleaning was adopted for some
final-cleaning applications. In some instances, aqueous cleaning is not
feasible.
For example,
in cleaning a sixty-foot long coil to be exposed
to refrigerant, any residue
of water
could produce catastrophic system failure.
For such applications, solvent cleaning was adopted. Solvents were
evaluated
in terms of performance,
cost, safety and environmental considerations
and
reliability. Initially, a brominated
solvent was selected; and the existing degreaser
was retrofitted. Commercially available flushing equipment was
determined to be unsuitable. To meet
the needs of in-house build and field repair,
a compact tube flushing station
was developed. In addition, BFK Solutions provided
appropriate
instructional seminars to in-house personnel
and to appropriate personnel from commercial
airlines.
References:
R. Petrulio. BE Aerospace et al, “A Practical Search Solves Aerospace Cleaning Quandry,” Precision Cleaning Magazine, Vol VI, p.22 - 31, August 1998.
R. Petrulio BE Aerospace and B. Kanegsberg BFK Solutions, “Practical Solutions to Cleaning and Flushing Problems,” Presentation and Proceedings, CleanTech ’98, Rosemont, IL, May 21, 1998.
Metal Stamping, Job Shop
• Select, implement airtight solvent system
• Maintain production throughput
• Sixty fold decrease in solvent emissions
A metal stamping facility was removing oils from a
variety of stamped metal products. Because the facility is a
job-shop, the product volume and mix varies markedly and unpredictably. There
is a wide assortment of metals; some of the products are very delicate
and readily
damaged
during process.
Parts were cleaned in large, open
top vapor degreasers.
Because of customer constraints, the company was using
HCFC’s;
one was very costly, the other would soon fall under
a usage ban. Solvent loss
was unacceptably
high. The company had expended extensive
time and financial resources in
an unproductive
attempt to introduce aqueous cleaning.
After reviewing the options, it was determined that the process would be most effectively and responsibly performed using a chlorinated solvent in an enclosed solvent system. Available systems were investigated in terms of cost, performance, reliability, throughput, and customer satisfaction. Solvents with effective stabilization packages, suitable for long-term use, were recommended. The project involved a review of national and local regulatory requirements as well as interaction with the local regulatory agency.
A large, airtight system with materials
handling capability was chosen
along with a semi-contained
back-up system.
The larger airtight
system
has resulted
in over a 60-fold decrease in solvent
emissions.
Metals
Precision Cleaning; Mixed Substrates (metal and non-metal)

