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RoHS
By Ed Kanegsberg


The RoHS deadline has arrived! What does this mean? RoHS is an acronym for “Restriction of the use of certain Hazardous Substances”, a directive of the European Union (EU) that restricts the use of six substances in most electrical and electronic equipment placed on the market after 1st July 2006. Although the primary focus in the electronics industry has been on elimination of lead from solders, the RoHS directive applications using Cadmium (Cd), mercury (Hg), hexavalent chromium (Cr (VI)), polybrominated biphenyls (PBBs) and polybrominated diphenyl ethers (PBDEs) as well as lead (Pb).


RoHS is a European directive. I’m in the US. Why does it affect me?


If you sell any equipment in any of the EU states or are an OEM of equipment that might be incorporated into systems sold in the EU, such equipment will need to comply with RoHS. However, even if your market is totally within the US, you will be affected. By January 1, 2007, some electronics sold in California will need to be RoHS compliant (please see accompanying article). Many other states and countries have either enacted or are considering similar legislation.


How Does RoHS Affect Cleaning?
The greatest impact of RoHS on electronic manufacturing is the conversion to lead-free solder. As with any process change, if the materials of construction change, the processes, including cleaning, need to adapt to new conditions.

Lead-free solder technology is still evolving. Some aspects of the technology that are evolving include solders, fluxes and reflow temperatures. These changing parameters mean that there will also need to be changes in both cleaning agents and processes. These modifications are likely to be application-specific. Other electronics assembly processes that will impact lead-free conversion include flipchip, BGA, and miniaturization. It is not sufficient just to adopt lead free solder. It is necessary to consider the total impact of all process changes.


Manufacturers worry about process change. Cleaning is costly due to capital outlay, process maintenance and labor requirements. Small changes can impact performance. In addition there are regulatory implications including ambiguous, conflicting rules. Employee safety/liability is always an issue. The manufacture needs a robust process to maintain or improve customer satisfaction and for improved profitability.


Cleaning with Lead-free Solders
Some testing by aqueous cleaning suppliers has been reported for cleaning lead-free solders. “No-clean” fluxes tend to leave residue if not cleaned [Bivens et. al (2000), Lee & Bixenman (2001)]. They found that the fluxes clean well with saponified aqueous processes but are not well cleaned by solvent degreasing.


Some issues with newer fluxes are that a higher reflow temperature has a higher oxidation rate, greater flux activity is needed to boost wettability and that higher tin content leads to more salts, that are harder to clean.


So, What should you do?
Changes with critical evaluation can be positive. Treat cleaning as a critical part of the overall process. Do not assume that the new fluxes will clean the same ways as the old. Understand the materials and what it takes to clean them
• TEST on your equipment
• TEST on your products


(Adapted from a presentation at the 2006 Del Mar (CA) Electronics Show. The presentation is available from BFK Solutions upon request).


References:
B.A. Bivins, A.A. Juan, B. Starkweather, N.C. Lee, and S. Negi, “Post-Solder Cleaning of Lead-Free Solder Paste Residues”, SMT International 2000, Chicago, IL, September, 2000.


N.C. Lee, and M. Bixenman, "Flux Technology For Lead-Free Alloys & Its Impact On Cleaning," 2001 Advanced Packaging Technology Conference Proceedings, Boston, 2001.

 

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