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Vapors and Product Quality
Barbara Kanegsberg,
BFK Solutions LLC


At an American Vacuum Society panel discussion earlier this month, I was asked a number of questions about the potential for residue from cleaning processes to negatively impact vacuum coatings and other engineered coatings. We tend to associate the negative impact of vapors with critical applications. However, vapors outgassing from the product can pose problems for many products.


What sorts of vapors are we talking about?
We’re concerned about a chemical that is adsorbed to the surface or near-surface of a product, fixture, or tool. The sorts of chemicals of concern depend on the situation and may include:
• Low boiling solvents
• Water
• High boiling solvents


What are some sources of outgassing materials?
• Ambient atmosphere
• Water or organic solvents used for cleaning
• Residue of cleaning agent additives
• Metalworking fluids
• Carrier fluids for deposition


What are examples where vapors might be a problem?
• Coated materials
• Sealed systems
• Critical operating environments
• Mixed metals, composites, and elastomers


If you have historical success with the product or process, there is less likely to be a concern with outgassing. The problems arise with new products, new uses of old products, and/or manufacturing process changes.


Outgassing is a concern for critical and industrial processes. To avoid outgassing problems, be alert and vigilant about changes. If you or your suppliers adopt a very high boiling solvent such as a bio-based solvent, residue may remain on the part. If the part is then exposed to high temperature for a long period of time or if it is used in a sealed system, the solvent may volatilize, contaminating other components or compromising coatings. If you purchase new cleaning equipment or process equipment, be alert to such details as the materials of construction of elastomers. If you change a fixture, check that coatings will not adsorb process chemicals.

 

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